Methylenediphenyl Diisocyanate CAS#101-68-8

Methylenediphenyl Diisocyanate CAS#101-68-8

Versatile Organic Chemistry Applications:Can be used as raw materials, intermediates, and reagents in organic chemical synthesis and high-performance polymer research.


Functional Material Development:Suitable for preparing functional materials, new material synthesis, and specialized chemical products.


Polymer and Additive Use:Applicable in polyurethane production, diphenylmethane derivatives, and as additives for polymers.


Analytical and Research Utility:Can be used for analyzing standard samples and in research involving pyridines, halogenated heterocycles, and isocyanate esters.



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product description

Products Description of Methylenediphenyl Diisocyanate CAS#101-68-8

4,4'-Diphenylmethane diisocyanate (MDI) and its derivatives are essential chemical industry materials. They are used in polyurethane production, as raw materials/intermediates for high-performance polymers, in functional material development, and in analytical research and chemical formulation additives.

Parameters


Melting point38-44 °C
Boiling point392 °C
density1.19
vapor pressure0.066 hPa (20 °C)
refractive index1.5906 (estimate)
Fp196 °C
storage temp.-20°C
solubility2g/l (decomposition)
formsolid
colorWhite to Almost white
Specific Gravity1.18
explose limit0.4%(V)
Water Solubilitydecomposes
FreezingPoint37℃
SensitiveMoisture Sensitive/Lachrymatory
BRN797662
Exposure limitsTLV-TWA 0.051 mg/m3 (0.005 ppm) (ACGIH and NIOSH); ceiling (air) 0.204 mg/m3 (0.02 ppm)/10 min (NIOSH and OSHA); IDLH 102 mg/m3 (10 ppm).
Dielectric constant10.0(Ambient)
Stability:Stable. Combustible. Incompatible with strong oxidizing agents. Reacts violently with alcohols.
CAS DataBase Reference101-68-8(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1,1'-methylenebis[4-isocyanato-(101-68-8)
IARC3 (Vol. 19, Sup 7, 71) 1999
EPA Substance Registry System4,4'-Methylenedi(phenyl isocyanate) (101-68-8)


Safety Information


Hazard CodesXn,T,C
Risk Statements42/43-36/37/38-20-48/20-40
Safety Statements45-36/37-23
RIDADR2206
OEBD
OELTWA: 0.05 mg/m3 (0.005 ppm), Ceiling: 0.2 mg/m3 (0.020 ppm) [10-minute]
WGK Germany1
RTECSNQ9350000
Autoignition Temperature>600 °C
Hazard NoteToxic/Corrosive/Lachrymatory/Moisture Sensitive
TSCAYes
HazardClass6.1
PackingGroupII
HS Code29291090
Hazardous Substances Data101-68-8(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 9000 mg/kg
IDLA75 mg/m3


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Shipping And Transportation

Delivery Time

Inventory 2-3 working days New manufacturing 7-10 working days

Mode of Transportation
1. By Air, fast but expensive.
2. By Sea, usual and economy.
3. By Train, suit for middle Asia countries.
4. By Express, suit for small package.
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3. What Are the Differences Between COA, SDS, and TDS?
A COA is a batch-specific Certificate of Analysis showing test items, required ranges, and actual results. It is mainly used for quality verification and incoming inspection.
An SDS provides safety, handling, storage, emergency, and transportation information. A TDS describes typical product properties, technical parameters, and application guidance. Buyers should confirm the required document version, language, and applicable standards before placing an order.


4. Key Conditions to Confirm Before International Chemical Transportation
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